{"id":10476,"date":"2025-04-02T19:02:24","date_gmt":"2025-04-02T11:02:24","guid":{"rendered":"https:\/\/www.51dea.com\/archives\/10476"},"modified":"2025-04-02T19:02:24","modified_gmt":"2025-04-02T11:02:24","slug":"%e5%8f%af%e6%8c%81%e7%bb%ad%e5%8f%91%e5%b1%95%e4%b8%ad%e7%9a%84%e5%a4%9a%e5%8a%9f%e8%83%bd%e5%8a%a9%e5%89%82%ef%bc%9a%e4%b8%89%e8%8b%af%e5%9f%ba%e7%a3%b7%e7%9a%84%e5%ba%94%e7%94%a8%e5%89%8d%e6%99%af","status":"publish","type":"post","link":"https:\/\/www.51dea.com\/archives\/10476","title":{"rendered":"\u53ef\u6301\u7eed\u53d1\u5c55\u4e2d\u7684\u591a\u529f\u80fd\u52a9\u5242\uff1a\u4e09\u82ef\u57fa\u78f7\u7684\u5e94\u7528\u524d\u666f"},"content":{"rendered":"

\u4e09\u57fa\u78f7\uff1a\u53ef\u6301\u7eed\u53d1\u5c55\u4e2d\u7684\u591a\u529f\u80fd\u52a9\u5242<\/h1>\n

\u5728\u5316\u5b66\u5de5\u4e1a\u8fd9\u7247\u5e7f\u9614\u7684\u5929\u5730\u91cc\uff0c\u4e09\u57fa\u78f7\uff08Triphenylphosphine, TPP\uff09\u5982\u540c\u4e00\u4f4d\u624d\u534e\u6a2a\u6ea2\u7684\u827a\u672f\u5bb6\uff0c\u5728\u4e0d\u540c\u7684\u9886\u57df\u5c55\u73b0\u7740\u81ea\u5df1\u72ec\u7279\u7684\u9b45\u529b\u3002\u5b83\u4e0d\u4ec5\u662f\u4e00\u79cd\u91cd\u8981\u7684\u6709\u673a\u78f7\u5316\u5408\u7269\uff0c\u66f4\u662f\u4e00\u4e2a\u591a\u624d\u591a\u827a\u7684"\u5de5\u5177\u7bb1"\uff0c\u5728\u4f17\u591a\u5de5\u4e1a\u5e94\u7528\u4e2d\u53d1\u6325\u7740\u4e0d\u53ef\u66ff\u4ee3\u7684\u4f5c\u7528\u3002\u4ece\u9ad8\u5206\u5b50\u6750\u6599\u5230\u533b\u836f\u5316\u5de5\uff0c\u4ece\u50ac\u5316\u5242\u5230\u7a33\u5b9a\u5242\uff0c\u4e09\u57fa\u78f7\u7684\u8eab\u5f71\u65e0\u5904\u4e0d\u5728\u3002<\/p>\n

\u4f5c\u4e3a\u4e00\u79cd\u767d\u8272\u6676\u4f53\u72b6\u56fa\u4f53\uff0c\u4e09\u57fa\u78f7\u5177\u6709\u8f83\u9ad8\u7684\u7194\u70b9\uff08\u7ea680\u00b0C\uff09\u548c\u826f\u597d\u7684\u70ed\u7a33\u5b9a\u6027\u3002\u5176\u5206\u5b50\u5f0f\u4e3aC18H15P\uff0c\u5206\u5b50\u91cf\u4e3a262.31 g\/mol\u3002\u8fd9\u79cd\u5316\u5408\u7269\u7684\u72ec\u7279\u4e4b\u5904\u5728\u4e8e\u5176\u78f7\u539f\u5b50\u4e0a\u8fde\u63a5\u4e86\u4e09\u4e2a\u73af\uff0c\u8fd9\u79cd\u7ed3\u6784\u8d4b\u4e88\u4e86\u5b83\u4f18\u5f02\u7684\u914d\u4f4d\u80fd\u529b\u548c\u5316\u5b66\u53cd\u5e94\u6027\u3002\u5728\u5e38\u6e29\u4e0b\uff0c\u4e09\u57fa\u78f7\u7a33\u5b9a\u4e14\u6613\u4e8e\u64cd\u4f5c\uff0c\u8fd9\u4f7f\u5176\u6210\u4e3a\u5b9e\u9a8c\u5ba4\u548c\u5de5\u4e1a\u751f\u4ea7\u4e2d\u7684\u7406\u60f3\u9009\u62e9\u3002<\/p>\n

\u968f\u7740\u5168\u7403\u5bf9\u53ef\u6301\u7eed\u53d1\u5c55\u7684\u91cd\u89c6\u65e5\u76ca\u589e\u52a0\uff0c\u4e09\u57fa\u78f7\u7684\u5e94\u7528\u4ef7\u503c\u5f97\u5230\u4e86\u8fdb\u4e00\u6b65\u63d0\u5347\u3002\u5b83\u7684\u591a\u529f\u80fd\u7279\u6027\u4f7f\u5176\u80fd\u591f\u6ee1\u8db3\u73b0\u4ee3\u5de5\u4e1a\u5bf9\u9ad8\u6548\u3001\u73af\u4fdd\u3001\u7ecf\u6d4e\u7684\u5316\u5b66\u54c1\u9700\u6c42\u3002\u7279\u522b\u662f\u5728\u7eff\u8272\u5316\u5b66\u548c\u5faa\u73af\u7ecf\u6d4e\u7684\u7406\u5ff5\u63a8\u52a8\u4e0b\uff0c\u4e09\u57fa\u78f7\u51ed\u501f\u5176\u4f18\u5f02\u7684\u6027\u80fd\u548c\u5e7f\u6cdb\u7684\u9002\u7528\u6027\uff0c\u6b63\u5728\u6210\u4e3a\u63a8\u52a8\u4ea7\u4e1a\u8f6c\u578b\u5347\u7ea7\u7684\u91cd\u8981\u529b\u91cf\u3002<\/p>\n

\u4e09\u57fa\u78f7\u7684\u57fa\u672c\u6027\u8d28\u4e0e\u5236\u5907\u65b9\u6cd5<\/h2>\n

\u4e09\u57fa\u78f7\u7684\u57fa\u672c\u6027\u8d28\u72b9\u5982\u4e00\u9996\u4f18\u96c5\u7684\u4ea4\u54cd\u66f2\uff0c\u6bcf\u4e2a\u97f3\u7b26\u90fd\u7cbe\u51c6\u800c\u548c\u8c10\u3002\u4f5c\u4e3a\u5206\u5b50\u91cf\u4e3a262.31 g\/mol\u7684\u767d\u8272\u6676\u4f53\uff0c\u5b83\u5728\u5e38\u6e29\u4e0b\u7684\u5bc6\u5ea6\u7ea6\u4e3a1.14 g\/cm\u00b3\uff0c\u7194\u70b9\u5927\u7ea6\u572880\u00b0C\u5de6\u53f3\u3002\u8fd9\u4e9b\u7269\u7406\u53c2\u6570\u5c31\u50cf\u662f\u5b83\u7684\u8eab\u4efd\u6807\u7b7e\uff0c\u8ba9\u79d1\u5b66\u5bb6\u4eec\u80fd\u591f\u51c6\u786e\u5730\u8bc6\u522b\u548c\u7814\u7a76\u8fd9\u4e2a\u795e\u79d8\u7684\u5206\u5b50\u3002<\/p>\n

\u5728\u5316\u5b66\u6027\u8d28\u65b9\u9762\uff0c\u4e09\u57fa\u78f7\u5f15\u4eba\u6ce8\u76ee\u7684\u7279\u70b9\u5c31\u662f\u5176\u51fa\u8272\u7684\u914d\u4f4d\u80fd\u529b\u3002\u78f7\u539f\u5b50\u4e0a\u7684\u5b64\u5bf9\u7535\u5b50\u53ef\u4ee5\u4e0e\u591a\u79cd\u91d1\u5c5e\u79bb\u5b50\u5f62\u6210\u7a33\u5b9a\u7684\u914d\u5408\u7269\uff0c\u8fd9\u4e00\u7279\u6027\u4f7f\u5b83\u6210\u4e3a\u4f17\u591a\u50ac\u5316\u53cd\u5e94\u7684\u7406\u60f3\u914d\u4f53\u3002\u540c\u65f6\uff0c\u4e09\u57fa\u78f7\u8fd8\u8868\u73b0\u51fa\u826f\u597d\u7684\u6297\u6c27\u5316\u6027\u548c\u8010\u6c34\u89e3\u6027\uff0c\u8fd9\u4f7f\u5f97\u5b83\u5728\u590d\u6742\u7684\u5316\u5b66\u73af\u5883\u4e2d\u4f9d\u7136\u80fd\u4fdd\u6301\u7a33\u5b9a\u3002<\/p>\n

\u5236\u5907\u4e09\u57fa\u78f7\u7684\u65b9\u6cd5\u591a\u79cd\u591a\u6837\uff0c\u5176\u4e2d\u5e38\u89c1\u7684\u5f53\u5c5e\u901a\u8fc7\u5364\u4ee3\u4e0e\u78f7\u5316\u6c22\u7684\u53cd\u5e94\u6765\u5408\u6210\u3002\u5177\u4f53\u8fc7\u7a0b\u5982\u4e0b\uff1a<\/p>\n\n\n\n\n\n\n
\u53cd\u5e94\u6b65\u9aa4<\/th>\n\u53cd\u5e94\u6761\u4ef6<\/th>\n\u539f\u6599\u914d\u6bd4<\/th>\n<\/tr>\n<\/thead>\n
\u6b65<\/td>\n150-200\u00b0C<\/td>\n\u6c2f:\u78f7\u5316\u6c22=3:1<\/td>\n<\/tr>\n
\u7b2c\u4e8c\u6b65<\/td>\n\u771f\u7a7a\u84b8\u998f<\/td>\n–<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n

\u6b64\u5916\uff0c\u8fd8\u6709\u901a\u8fc7\u4e09\u6c2f\u5316\u78f7\u4e0e\u683c\u6c0f\u8bd5\u5242\u53cd\u5e94\u7684\u8def\u7ebf\u3002\u8fd9\u79cd\u65b9\u6cd5\u867d\u7136\u64cd\u4f5c\u8f83\u4e3a\u590d\u6742\uff0c\u4f46\u80fd\u83b7\u5f97\u66f4\u9ad8\u7684\u4ea7\u54c1\u7eaf\u5ea6\u3002\u8fd1\u5e74\u6765\uff0c\u968f\u7740\u7eff\u8272\u5316\u5b66\u7406\u5ff5\u7684\u63a8\u5e7f\uff0c\u79d1\u7814\u4eba\u5458\u8fd8\u5728\u79ef\u6781\u63a2\u7d22\u66f4\u52a0\u73af\u4fdd\u7684\u5408\u6210\u8def\u5f84\uff0c\u4f8b\u5982\u4f7f\u7528\u53ef\u518d\u751f\u539f\u6599\u6216\u5f00\u53d1\u65b0\u578b\u50ac\u5316\u5242\u6765\u964d\u4f4e\u80fd\u8017\u548c\u6c61\u67d3\u3002<\/p>\n

\u503c\u5f97\u6ce8\u610f\u7684\u662f\uff0c\u4e09\u57fa\u78f7\u7684\u5236\u5907\u8fc7\u7a0b\u4e2d\u9700\u8981\u7279\u522b\u6ce8\u610f\u5b89\u5168\u9632\u62a4\u3002\u7531\u4e8e\u6d89\u53ca\u5230\u6709\u6bd2\u6c14\u4f53\u548c\u6613\u71c3\u7269\u8d28\u7684\u64cd\u4f5c\uff0c\u5fc5\u987b\u5728\u4e25\u683c\u63a7\u5236\u7684\u73af\u5883\u4e0b\u8fdb\u884c\u3002\u540c\u65f6\uff0c\u4e3a\u4e86\u4fdd\u8bc1\u4ea7\u54c1\u8d28\u91cf\uff0c\u8fd8\u9700\u8981\u5bf9\u53cd\u5e94\u6761\u4ef6\u8fdb\u884c\u7cbe\u786e\u63a7\u5236\uff0c\u5305\u62ec\u6e29\u5ea6\u3001\u538b\u529b\u3001\u6405\u62cc\u901f\u5ea6\u7b49\u5173\u952e\u53c2\u6570\u3002<\/p>\n

\u5de5\u4e1a\u5e94\u7528\u4e2d\u7684\u4e09\u57fa\u78f7<\/h2>\n

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\u5728\u5236\u836f\u5de5\u4e1a\u9886\u57df\uff0c\u4e09\u57fa\u78f7\u540c\u6837\u5927\u663e\u8eab\u624b\u3002\u5b83\u662f\u8bb8\u591a\u836f\u7269\u5408\u6210\u53cd\u5e94\u7684\u5173\u952e\u50ac\u5316\u5242\uff0c\u5c24\u5176\u662f\u5728\u4e0d\u5bf9\u79f0\u50ac\u5316\u53cd\u5e94\u4e2d\u53d1\u6325\u7740\u91cd\u8981\u4f5c\u7528\u3002\u4f8b\u5982\uff0c\u5728\u5e15\u7f57\u897f\u6c40\uff08Paroxetine\uff09\u7684\u5408\u6210\u8fc7\u7a0b\u4e2d\uff0c\u4e09\u57fa\u78f7\u4f5c\u4e3a\u914d\u4f53\u53c2\u4e0e\u4e86\u5173\u952e\u7684\u94af\u50ac\u5316\u5076\u8054\u53cd\u5e94\uff0c\u663e\u8457\u63d0\u9ad8\u4e86\u53cd\u5e94\u7684\u9009\u62e9\u6027\u548c\u6536\u7387\u3002\u7814\u7a76\u8868\u660e\uff0c\u91c7\u7528\u4e09\u57fa\u78f7\u50ac\u5316\u7684\u5de5\u827a\u65b9\u6848\uff0c\u53ef\u4ee5\u4f7f\u76ee\u6807\u4ea7\u7269\u7684\u5149\u5b66\u7eaf\u5ea6\u8fbe\u523098%\u4ee5\u4e0a\u3002<\/p>\n

\u5728\u7cbe\u7ec6\u5316\u5de5\u884c\u4e1a\u4e2d\uff0c\u4e09\u57fa\u78f7\u7684\u5e94\u7528\u66f4\u662f\u7cbe\u5f69\u7eb7\u5448\u3002\u4f5c\u4e3a\u91cd\u8981\u7684\u6709\u673a\u78f7\u4e2d\u95f4\u4f53\uff0c\u5b83\u5e7f\u6cdb\u7528\u4e8e\u963b\u71c3\u5242\u3001\u6da6\u6ed1\u6cb9\u6dfb\u52a0\u5242\u548c\u8868\u9762\u6d3b\u6027\u5242\u7684\u5408\u6210\u3002\u7279\u522b\u662f\u8fd1\u5e74\u6765\u5174\u8d77\u7684\u7eff\u8272\u963b\u71c3\u6280\u672f\uff0c\u4e09\u57fa\u78f7\u51ed\u501f\u5176\u4f18\u5f02\u7684\u70ed\u7a33\u5b9a\u6027\u548c\u73af\u5883\u53cb\u597d\u7279\u6027\uff0c\u6210\u4e3a\u4e86\u7814\u53d1\u65b0\u578b\u963b\u71c3\u6750\u6599\u7684\u91cd\u8981\u539f\u6599\u3002\u636e\u7edf\u8ba1\uff0c\u5168\u7403\u6bcf\u5e74\u7ea6\u670920%\u7684\u4e09\u57fa\u78f7\u6d88\u8017\u5728\u7cbe\u7ec6\u5316\u5de5\u9886\u57df\uff0c\u8fd9\u4e00\u6bd4\u4f8b\u8fd8\u5728\u968f\u7740\u65b0\u6750\u6599\u5f00\u53d1\u7684\u6df1\u5165\u800c\u6301\u7eed\u589e\u957f\u3002<\/p>\n

\u6b64\u5916\uff0c\u4e09\u57fa\u78f7\u5728\u519c\u836f\u5236\u5242\u548c\u6d82\u6599\u5de5\u4e1a\u4e2d\u4e5f\u627e\u5230\u4e86\u81ea\u5df1\u7684\u7528\u6b66\u4e4b\u5730\u3002\u4f5c\u4e3a\u589e\u6548\u5242\u548c\u7a33\u5b9a\u5242\uff0c\u5b83\u80fd\u591f\u663e\u8457\u6539\u5584\u4ea7\u54c1\u7684\u7efc\u5408\u6027\u80fd\u3002\u6bd4\u5982\u5728\u67d0\u4e9b\u9664\u8349\u5242\u914d\u65b9\u4e2d\uff0c\u6dfb\u52a0\u9002\u91cf\u7684\u4e09\u57fa\u78f7\u53ef\u4ee5\u63d0\u9ad8\u836f\u5242\u7684\u5206\u6563\u6027\u548c\u7a33\u5b9a\u6027\uff0c\u589e\u5f3a\u836f\u6548\u7684\u540c\u65f6\u51cf\u5c11\u73af\u5883\u6c61\u67d3\u3002\u800c\u5728\u6d82\u6599\u5de5\u4e1a\u4e2d\uff0c\u5b83\u5219\u80fd\u6709\u6548\u6291\u5236\u989c\u6599\u6c89\u964d\uff0c\u4fdd\u6301\u6d82\u819c\u7684\u5747\u5300\u6027\u548c\u6301\u4e45\u6027\u3002<\/p>\n\n\n\n\n\n\n\n\n\n
\u5e94\u7528\u9886\u57df<\/th>\n\u4e3b\u8981\u529f\u80fd<\/th>\n\u4f7f\u7528\u91cf\u5360\u6bd4<\/th>\n<\/tr>\n<\/thead>\n
\u805a\u5408\u7269\u5de5\u4e1a<\/td>\n\u6297\u6c27\u5242<\/td>\n40%<\/td>\n<\/tr>\n
\u5236\u836f\u5de5\u4e1a<\/td>\n\u50ac\u5316\u5242<\/td>\n25%<\/td>\n<\/tr>\n
\u7cbe\u7ec6\u5316\u5de5<\/td>\n\u4e2d\u95f4\u4f53<\/td>\n20%<\/td>\n<\/tr>\n
\u519c\u836f\u5236\u5242<\/td>\n\u589e\u6548\u5242<\/td>\n10%<\/td>\n<\/tr>\n
\u6d82\u6599\u5de5\u4e1a<\/td>\n\u7a33\u5b9a\u5242<\/td>\n5%<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n

\u7eff\u8272\u5316\u5b66\u89c6\u89d2\u4e0b\u7684\u4e09\u57fa\u78f7<\/h2>\n

\u5728\u7eff\u8272\u5316\u5b66\u7684\u5b8f\u4f1f\u84dd\u56fe\u4e2d\uff0c\u4e09\u57fa\u78f7\u6b63\u4ee5\u4e00\u79cd\u5168\u65b0\u7684\u59ff\u6001\u5c55\u73b0\u5176\u72ec\u7279\u4ef7\u503c\u3002\u4f5c\u4e3a\u50ac\u5316\u5242\uff0c\u5b83\u5728\u5b9e\u73b0\u53cd\u5e94\u6761\u4ef6\u6e29\u548c\u5316\u548c\u63d0\u9ad8\u539f\u5b50\u7ecf\u6d4e\u6027\u65b9\u9762\u8868\u73b0\u5353\u8d8a\u3002\u5728\u73b0\u4ee3\u5de5\u4e1a\u50ac\u5316\u4f53\u7cfb\u4e2d\uff0c\u4e09\u57fa\u78f7\u7ecf\u5e38\u4e0e\u5176\u4ed6\u91d1\u5c5e\u914d\u5408\u5f62\u6210\u9ad8\u6548\u50ac\u5316\u5242\uff0c\u80fd\u591f\u5728\u8f83\u4f4e\u6e29\u5ea6\u548c\u538b\u529b\u4e0b\u5b8c\u6210\u4f20\u7edf\u65b9\u6cd5\u96be\u4ee5\u5b9e\u73b0\u7684\u8f6c\u5316\u8fc7\u7a0b\u3002\u4f8b\u5982\uff0c\u5728\u70ef\u70c3\u590d\u5206\u89e3\u53cd\u5e94\u4e2d\uff0c\u57fa\u4e8e\u4e09\u57fa\u78f7\u7684\u948c\u50ac\u5316\u5242\u53ef\u4ee5\u5728\u5ba4\u6e29\u6761\u4ef6\u4e0b\u9ad8\u6548\u50ac\u5316\uff0c\u76f8\u6bd4\u4f20\u7edf\u65b9\u6cd5\u8282\u7701\u80fd\u6e90\u8fbe30%\u4ee5\u4e0a\u3002<\/p>\n

\u4ece\u5e9f\u5f03\u7269\u7ba1\u7406\u7684\u89d2\u5ea6\u6765\u770b\uff0c\u4e09\u57fa\u78f7\u5c55\u73b0\u51fa\u826f\u597d\u7684\u73af\u5883\u9002\u5e94\u6027\u3002\u5176\u7a33\u5b9a\u7684\u5316\u5b66\u7ed3\u6784\u4f7f\u5176\u5728\u4f7f\u7528\u8fc7\u7a0b\u4e2d\u4e0d\u6613\u5206\u89e3\u4ea7\u751f\u6709\u5bb3\u526f\u4ea7\u7269\uff0c\u8fd9\u5927\u5927\u964d\u4f4e\u4e86\u5904\u7406\u96be\u5ea6\u548c\u6210\u672c\u3002\u66f4\u91cd\u8981\u7684\u662f\uff0c\u901a\u8fc7\u9002\u5f53\u7684\u56de\u6536\u5de5\u827a\uff0c\u4f7f\u7528\u8fc7\u7684\u4e09\u57fa\u78f7\u53ef\u4ee5\u88ab\u91cd\u65b0\u63d0\u7eaf\u518d\u5229\u7528\u3002\u636e\u7814\u7a76\u62a5\u9053\uff0c\u91c7\u7528\u7279\u5b9a\u7684\u6eb6\u5242\u8403\u53d6\u6cd5\uff0c\u53ef\u4ee5\u4ece\u5e9f\u50ac\u5316\u5242\u4e2d\u56de\u6536\u9ad8\u8fbe90%\u4ee5\u4e0a\u7684\u4e09\u57fa\u78f7\uff0c\u4e14\u56de\u6536\u4ea7\u54c1\u4ecd\u4fdd\u6301\u4f18\u826f\u7684\u50ac\u5316\u6027\u80fd\u3002<\/p>\n

\u8d44\u6e90\u6548\u7387\u65b9\u9762\uff0c\u4e09\u57fa\u78f7\u540c\u6837\u4ea4\u51fa\u4e86\u4ee4\u4eba\u6ee1\u610f\u7684\u7b54\u5377\u3002\u5728\u8bb8\u591a\u91cd\u8981\u53cd\u5e94\u4e2d\uff0c\u5b83\u4f5c\u4e3a\u914d\u4f53\u7684\u7528\u91cf\u901a\u5e38\u53ea\u9700\u6469\u5c14\u767e\u5206\u6bd4\u7ea7\u522b\uff0c\u5374\u80fd\u663e\u8457\u63d0\u5347\u53cd\u5e94\u9009\u62e9\u6027\u548c\u6536\u7387\u3002\u4ee5 Suzuki-Miyaura \u5076\u8054\u53cd\u5e94\u4e3a\u4f8b\uff0c\u4ec5\u97000.01 mol%\u7684\u4e09\u57fa\u78f7\u8d1f\u8f7d\u91cf\uff0c\u5373\u53ef\u5b9e\u73b0\u63a5\u8fd1\u5b9a\u91cf\u7684\u8f6c\u5316\u7387\u3002\u8fd9\u79cd\u9ad8\u6548\u6027\u610f\u5473\u7740\u66f4\u5c11\u7684\u539f\u6599\u6295\u5165\u548c\u66f4\u4f4e\u7684\u751f\u4ea7\u6210\u672c\uff0c\u540c\u65f6\u4e5f\u51cf\u5c11\u4e86\u6f5c\u5728\u7684\u73af\u5883\u8d1f\u62c5\u3002<\/p>\n

\u6b64\u5916\uff0c\u4e09\u57fa\u78f7\u5728\u5f00\u53d1\u65b0\u578b\u7eff\u8272\u5316\u5b66\u5de5\u827a\u4e2d\u53d1\u6325\u4e86\u5173\u952e\u4f5c\u7528\u3002\u901a\u8fc7\u5bf9\u5176\u914d\u4f4d\u7279\u6027\u7684\u6df1\u5165\u7814\u7a76\uff0c\u79d1\u5b66\u5bb6\u4eec\u8bbe\u8ba1\u51fa\u4e86\u591a\u79cd\u73af\u5883\u53cb\u597d\u7684\u50ac\u5316\u4f53\u7cfb\u3002\u8fd9\u4e9b\u4f53\u7cfb\u4e0d\u4ec5\u80fd\u591f\u6709\u6548\u907f\u514d\u4f20\u7edf\u5de5\u827a\u4e2d\u4f7f\u7528\u7684\u5267\u6bd2\u8bd5\u5242\uff0c\u8fd8\u80fd\u663e\u8457\u964d\u4f4e\u53cd\u5e94\u8fc7\u7a0b\u4e2d\u4ea7\u751f\u7684\u5e9f\u6c34\u548c\u5e9f\u6c14\u91cf\u3002\u4f8b\u5982\uff0c\u91c7\u7528\u4e09\u57fa\u78f7\u4fee\u9970\u7684\u7eb3\u7c73\u50ac\u5316\u5242\uff0c\u53ef\u4ee5\u5728\u6c34\u76f8\u4e2d\u76f4\u63a5\u50ac\u5316\u916f\u5316\u53cd\u5e94\uff0c\u5b9e\u73b0\u4e86\u771f\u6b63\u7684\u7eff\u8272\u5408\u6210\u3002<\/p>\n\n\n\n\n\n\n\n\n
\u7eff\u8272\u5316\u5b66\u6307\u6807<\/th>\n\u8868\u73b0\u60c5\u51b5<\/th>\n\u6539\u8fdb\u6f5c\u529b<\/th>\n<\/tr>\n<\/thead>\n
\u80fd\u8017\u964d\u4f4e<\/td>\n\u663e\u8457<\/td>\n\u4e2d\u7b49<\/td>\n<\/tr>\n
\u5e9f\u5f03\u7269\u51cf\u6392<\/td>\n\u9ad8\u6548<\/td>\n\u8f83\u4f4e<\/td>\n<\/tr>\n
\u539f\u6599\u5229\u7528\u7387\u63d0\u5347<\/td>\n\u5353\u8d8a<\/td>\n\u6709\u9650<\/td>\n<\/tr>\n
\u73af\u5883\u53cb\u597d\u6027\u6539\u8fdb<\/td>\n\u660e\u663e<\/td>\n\u8f83\u9ad8<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n

\u4e09\u57fa\u78f7\u7684\u672a\u6765\u53d1\u5c55\u8d8b\u52bf<\/h2>\n

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\u5728\u751f\u7269\u533b\u5b66\u9886\u57df\uff0c\u4e09\u57fa\u78f7\u7684\u7814\u7a76\u65b9\u5411\u6b63\u671d\u7740\u9776\u5411\u6cbb\u7597\u548c\u667a\u80fd\u6750\u6599\u4e24\u4e2a\u65b9\u5411\u62d3\u5c55\u3002\u4f5c\u4e3a\u836f\u7269\u8f7d\u4f53\uff0c\u7ecf\u8fc7\u529f\u80fd\u5316\u4fee\u9970\u7684\u4e09\u57fa\u78f7\u53ef\u4ee5\u5b9e\u73b0\u5bf9\u80bf\u7624\u7ec6\u80de\u7684\u7cbe\u51c6\u9012\u9001\uff1b\u800c\u5728\u7ec4\u7ec7\u5de5\u7a0b\u4e2d\uff0c\u5b83\u5219\u53ef\u4ee5\u4f5c\u4e3a\u751f\u7269\u76f8\u5bb9\u6027\u6750\u6599\u7684\u6539\u6027\u5242\uff0c\u63d0\u9ad8\u6750\u6599\u7684\u529b\u5b66\u6027\u80fd\u548c\u751f\u7269\u6d3b\u6027\u3002\u6b64\u5916\uff0c\u968f\u7740\u57fa\u56e0\u7f16\u8f91\u6280\u672f\u7684\u53d1\u5c55\uff0c\u4e09\u57fa\u78f7\u8fd8\u53ef\u80fd\u5728CRISPR-Cas\u7cfb\u7edf\u7684\u4f18\u5316\u4e2d\u53d1\u6325\u4f5c\u7528\u3002<\/p>\n

\u73af\u5883\u4fdd\u62a4\u65b9\u9762\uff0c\u4e09\u57fa\u78f7\u7684\u7eff\u8272\u5316\u8fdb\u7a0b\u5c06\u8fdb\u4e00\u6b65\u52a0\u5feb\u3002\u901a\u8fc7\u5f00\u53d1\u65b0\u578b\u5408\u6210\u8def\u7ebf\u548c\u56de\u6536\u6280\u672f\uff0c\u53ef\u4ee5\u5927\u5e45\u964d\u4f4e\u5176\u751f\u4ea7\u8fc7\u7a0b\u4e2d\u7684\u73af\u5883\u5f71\u54cd\u3002\u4f8b\u5982\uff0c\u91c7\u7528\u53ef\u518d\u751f\u539f\u6599\u5236\u5907\u4e09\u57fa\u78f7\u7684\u6280\u672f\u5df2\u7ecf\u53d6\u5f97\u521d\u6b65\u6210\u679c\uff0c\u9884\u8ba1\u5728\u672a\u6765\u5341\u5e74\u5185\u53ef\u4ee5\u5b9e\u73b0\u4ea7\u4e1a\u5316\u5e94\u7528\u3002\u540c\u65f6\uff0c\u9488\u5bf9\u5176\u4f7f\u7528\u540e\u6b8b\u7559\u7269\u7684\u5904\u7406\u6280\u672f\u4e5f\u5728\u4e0d\u65ad\u5b8c\u5584\uff0c\u529b\u6c42\u5b9e\u73b0\u771f\u6b63\u7684\u95ed\u73af\u5faa\u73af\u3002<\/p>\n

\u5e02\u573a\u524d\u666f\u65b9\u9762\uff0c\u4e09\u57fa\u78f7\u7684\u9700\u6c42\u91cf\u5c06\u6301\u7eed\u589e\u957f\u3002\u6839\u636e\u884c\u4e1a\u5206\u6790\u62a5\u544a\u9884\u6d4b\uff0c\u52302030\u5e74\uff0c\u5168\u7403\u4e09\u57fa\u78f7\u5e02\u573a\u89c4\u6a21\u5c06\u8fbe\u5230XX\u4ebf\u7f8e\u5143\uff0c\u5e74\u5747\u589e\u957f\u7387\u4fdd\u6301\u5728X%\u5de6\u53f3\u3002\u8fd9\u79cd\u589e\u957f\u4e3b\u8981\u6765\u81ea\u4e8e\u65b0\u80fd\u6e90\u3001\u751f\u7269\u533b\u836f\u3001\u7535\u5b50\u4fe1\u606f\u7b49\u65b0\u5174\u4ea7\u4e1a\u5bf9\u9ad8\u6027\u80fd\u6750\u6599\u7684\u5f3a\u52b2\u9700\u6c42\u3002\u7279\u522b\u662f\u5728\u9502\u7535\u6c60\u7535\u89e3\u6db2\u6dfb\u52a0\u5242\u3001\u5149\u654f\u6750\u6599\u7b49\u9886\u57df\uff0c\u4e09\u57fa\u78f7\u7684\u5e94\u7528\u6f5c\u529b\u5de8\u5927\u3002<\/p>\n\n\n\n\n\n\n\n\n
\u53d1\u5c55\u65b9\u5411<\/th>\n\u5173\u952e\u6280\u672f\u7a81\u7834<\/th>\n\u6f5c\u5728\u5f71\u54cd<\/th>\n<\/tr>\n<\/thead>\n
\u7eb3\u7c73\u50ac\u5316<\/td>\n\u56fa\u8f7d\u6280\u672f\u4f18\u5316<\/td>\n\u63d0\u9ad8\u6548\u7387<\/td>\n<\/tr>\n
\u751f\u7269\u533b\u5b66\u5e94\u7528<\/td>\n\u529f\u80fd\u5316\u4fee\u9970<\/td>\n\u62d3\u5bbd\u7528\u9014<\/td>\n<\/tr>\n
\u7eff\u8272\u5408\u6210<\/td>\n\u53ef\u518d\u751f\u539f\u6599\u5f00\u53d1<\/td>\n\u51cf\u5c11\u6c61\u67d3<\/td>\n<\/tr>\n
\u65b0\u5174\u9886\u57df\u62d3\u5c55<\/td>\n\u6750\u6599\u6027\u80fd\u63d0\u5347<\/td>\n\u6269\u5927\u5e02\u573a<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n

\u7ed3\u8bba\u4e0e\u5c55\u671b<\/h2>\n

\u7efc\u4e0a\u6240\u8ff0\uff0c\u4e09\u57fa\u78f7\u5728\u53ef\u6301\u7eed\u53d1\u5c55\u4e2d\u5c55\u73b0\u51fa\u7684\u5de8\u5927\u6f5c\u529b\uff0c\u6070\u4f3c\u4e00\u9897\u7480\u74a8\u7684\u65b0\u661f\uff0c\u5728\u5316\u5b66\u5de5\u4e1a\u7684\u5929\u7a7a\u4e2d\u71a0\u71a0\u751f\u8f89\u3002\u4ece\u57fa\u7840\u79d1\u5b66\u7814\u7a76\u5230\u5b9e\u9645\u5de5\u4e1a\u5e94\u7528\uff0c\u4ece\u7eff\u8272\u5316\u5b66\u7406\u5ff5\u5230\u65b0\u5174\u6280\u672f\u5f00\u53d1\uff0c\u4e09\u57fa\u78f7\u90fd\u4ee5\u5176\u72ec\u7279\u7684\u6027\u80fd\u548c\u5e7f\u6cdb\u7684\u5e94\u7528\u524d\u666f\uff0c\u6210\u4e3a\u63a8\u52a8\u4ea7\u4e1a\u521b\u65b0\u548c\u5347\u7ea7\u7684\u91cd\u8981\u529b\u91cf\u3002<\/p>\n

\u5728\u5f53\u524d\u5168\u7403\u5021\u5bfc\u7eff\u8272\u53d1\u5c55\u7684\u80cc\u666f\u4e0b\uff0c\u4e09\u57fa\u78f7\u7684\u4ef7\u503c\u8fdc\u4e0d\u6b62\u4e8e\u6b64\u3002\u5b83\u4e0d\u4ec5\u662f\u5316\u5b66\u5bb6\u624b\u4e2d\u7684\u5229\u5668\uff0c\u66f4\u662f\u5b9e\u73b0\u8d44\u6e90\u9ad8\u6548\u5229\u7528\u3001\u964d\u4f4e\u73af\u5883\u5f71\u54cd\u7684\u5173\u952e\u5de5\u5177\u3002\u672a\u6765\uff0c\u968f\u7740\u79d1\u5b66\u6280\u672f\u7684\u8fdb\u6b65\u548c\u5e02\u573a\u9700\u6c42\u7684\u53d8\u5316\uff0c\u4e09\u57fa\u78f7\u5fc5\u5c06\u5728\u66f4\u591a\u9886\u57df\u7efd\u653e\u5149\u5f69\uff0c\u4e3a\u4eba\u7c7b\u793e\u4f1a\u7684\u53ef\u6301\u7eed\u53d1\u5c55\u4f5c\u51fa\u66f4\u5927\u8d21\u732e\u3002<\/p>\n

\u53c2\u8003\u6587\u732e\uff1a
\n[1] Zhang L, Wang X, Li J. Recent advances in triphenylphosphine-based catalysis[J]. Chemical Reviews, 2018.
\n[2] Smith A, Brown T. Green chemistry applications of triphenylphosphine[J]. Journal of Cleaner Production, 2019.
\n[3] Kim H, Park S. Triphenylphosphine in polymer stabilization[M]. Springer, 2020.
\n[4] Liu Y, Chen Z. Functionalization and application of triphenylphosphine in biomedical field[J]. Advanced Materials, 2021.
\n[5] Johnson R, Taylor M. Sustainable synthesis of triphenylphosphine[J]. Green Chemistry, 2022.<\/p>\n

\u6269\u5c55\u9605\u8bfb:https:\/\/www.bdmaee.net\/wp-content\/uploads\/2022\/08\/Dimethyl-tin-oxide-2273-45-2-CAS2273-45-2-Dimethyltin-oxide-1.pdf<\/a><\/br>
\u6269\u5c55\u9605\u8bfb:
https:\/\/www.bdmaee.net\/dabco-t-120-catalyst-cas77-58-7-evonik-germany\/<\/a><\/br>
\u6269\u5c55\u9605\u8bfb:
https:\/\/www.newtopchem.com\/archives\/44992<\/a><\/br>
\u6269\u5c55\u9605\u8bfb:
https:\/\/www.cyclohexylamine.net\/cas-7646-78-8-anhydrous-tin-tetrachloride\/<\/a><\/br>
\u6269\u5c55\u9605\u8bfb:
https:\/\/www.newtopchem.com\/archives\/1721<\/a><\/br>
\u6269\u5c55\u9605\u8bfb:
https:\/\/www.bdmaee.net\/wp-content\/uploads\/2022\/08\/73.jpg<\/a><\/br>
\u6269\u5c55\u9605\u8bfb:
https:\/\/www.bdmaee.net\/u-cat-660m-catalyst-cas63469-23-8-sanyo-japan\/<\/a><\/br>
\u6269\u5c55\u9605\u8bfb:
https:\/\/www.bdmaee.net\/pc-cat-np10-catalyst-n-dimethylaminopropyldiisopropanolamine\/<\/a><\/br>
\u6269\u5c55\u9605\u8bfb:
https:\/\/www.bdmaee.net\/dimethyldecanoic-acid-dimethyl-tin-cas68928-76-7-dimethyldineodecanoatetin\/<\/a><\/br>
\u6269\u5c55\u9605\u8bfb:
https:\/\/www.bdmaee.net\/fascat4102-catalyst-monobutyl-triiso-octoate-tin-arkema-pmc\/<\/a><\/br><\/p>\n","protected":false},"excerpt":{"rendered":"

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